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dc.contributor.author | Dickie, Diane A.![]() |
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dc.contributor.author | Chacon, Brittany E.![]() |
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dc.contributor.author | Issabekov, Alibek![]() |
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dc.contributor.author | Lam, Kevin![]() |
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dc.contributor.author | Kemp, Richard A.![]() |
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dc.creator | Diane A., Dickie | |
dc.date.accessioned | 2017-12-21T06:12:44Z | |
dc.date.available | 2017-12-21T06:12:44Z | |
dc.date.issued | 2016-11-01 | |
dc.identifier | DOI:10.1016/j.ica.2016.07.048 | |
dc.identifier.citation | Diane A. Dickie, Brittany E. Chacon, Alibek Issabekov, Kevin Lam, Richard A. Kemp, Nickel(II) and nickel(0) complexes of bis(diisopropylphosphino)amine: Synthesis, structure, and electrochemical activity, In Inorganica Chimica Acta, Volume 453, 2016, Pages 42-50 | en_US |
dc.identifier.issn | 00201693 | |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0020169316304261 | |
dc.identifier.uri | http://nur.nu.edu.kz/handle/123456789/3004 | |
dc.description.abstract | Abstract In its neutral state, bis(diisopropylphosphino)amine HL reacts in equimolar amounts with the nickel halides NiCl2·6H2O, NiBr2, and NiI2 in ethanol solutions to give the air- and moisture-stable P,P-chelated complexes (HL)NiX2 (X=Cl, Br, I). Under similar conditions, complexes of the form [(HL)2Ni]X2 (X=BF4, NO3, ClO4) were prepared from 2:1 ligand-metal ratios of Ni(BF4)2·6H2O, Ni(NO3)2·6H2O, or Ni(ClO4)2·6H2O. Deprotonation of the ligand with NaNH2 followed by reaction with NiI2 gives L2Ni when performed in Et2O, but leads to the co-crystal L2Ni·2[NCCHC(Me)NH2] when the solvent is acetonitrile. In addition to these Ni2+ compounds, the Ni0 complex (HL)2Ni can be prepared from a toluene solution of Ni(cod)2. Each complex has been characterized by a combination of IR and multi-nuclear NMR spectroscopies, as well as single-crystal X-ray diffraction. Electrochemical studies of the complexes revealed irreversible decomposition of the (HL)NiX2 (X=Cl, Br, I) series, but electrocatalytic CO2 reduction by the [(HL)2Ni]X2 (X=BF4, NO3, ClO4) compounds. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Inorganica Chimica Acta | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | |
dc.subject | X-ray structures | en_US |
dc.subject | Nickel complexes | en_US |
dc.subject | Electrochemistry | en_US |
dc.subject | CO2 reactions | en_US |
dc.subject | Phosphorus ligands | en_US |
dc.title | Nickel(II) and nickel(0) complexes of bis(diisopropylphosphino)amine: Synthesis, structure, and electrochemical activity | en_US |
dc.type | Article | en_US |
dc.rights.license | © 2016 Elsevier B.V. All rights reserved. | |
elsevier.identifier.doi | 10.1016/j.ica.2016.07.048 | |
elsevier.identifier.eid | 1-s2.0-S0020169316304261 | |
elsevier.identifier.pii | S0020-1693(16)30426-1 | |
elsevier.identifier.scopusid | 84980324226 | |
elsevier.volume | 453 | |
elsevier.coverdate | 2016-11-01 | |
elsevier.coverdisplaydate | 1 November 2016 | |
elsevier.startingpage | 42 | |
elsevier.endingpage | 50 | |
elsevier.openaccess | 0 | |
elsevier.openaccessarticle | false | |
elsevier.openarchivearticle | false | |
elsevier.teaser | In its neutral state, bis(diisopropylphosphino)amine HL reacts in equimolar amounts with the nickel halides NiCl2·6H2O, NiBr2, and NiI2 in ethanol solutions to give the air- and moisture-stable P,P-chelated... | |
elsevier.aggregationtype | Journal | |
workflow.import.source | science |
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