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Item Open Access Influence of plasma exposure on physical characteristics of thin films of SnO2 obtained from SnCl4 solutions with additives of NH4F and NH4OH(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Mukhamedshina, D.M.; Fedosimova, A. I.; Dmitrieva, E.A.; Lebedev, I. A.; Grushevskaya, E. A.; Ibraimova, S.A.; Mit, K.A.; Serikkanov, A.S.The electrical conductivity of tin dioxide is extremely sensitive to the state of the surface in the temperature range 300-800 K, at which oxidation-reduction reactions take place on its surface. Nanocrystalline films of tin dioxide are selectively sensitive to the presence of toxic gases, organic and certain biological molecules in the surrounding atmosphere [1]. SnO2-based films are also used as transparent conductive coatings [2]. To modify the properties of the films, alloying, heat treatment, plasma treatment is used.Item Open Access Electric Current Generation in the System Polyelectrolyte Gel of V2O5 – Solution(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Kopishev, Eldar; Suleimenov, Ibrahim; Syzdykov, Askar; Safarov, Ruslan; Mashan, Togzhan; Berdenov, ZharasExtending the list of the physical and chemical processes applicable for making electric current accumulators allows expanding the sources of raw material for the production of this category of goods. Vanadium is a promising alternative to lithium. In this paper, we describe the generation of an electric current in the dissolution of gels based on vanadium (V) oxide. It was shown that an electrochemical cell having the properties of a battery of electric energy can be produced by using decavanadic acid gel and hydroxide solution. In particular, it was theoretically established that a sample of a gel that passed into a collapsed state under the influence of a constant electric current has an ability to generate an electric current in a closed galvanic circuit after an external current source was disconnected. The gel was grown from an aqueous solution of vanadium (V) oxide. The dependence of the amperage in the external circuit on time is shown, the starting value of the discharge current J0 is indicated. During the experiments, the generation of current was also studied by placing the gel sample into the solutions of other substances, as well as into the distilled water. It was found that in acid solutions and pure water, the efficiency of the current generation is very low (the current values obtained do not exceed the sensitivity limit of the microammeter). The generation of current becomes effective only by placing the gel in an alkali solution.Item Open Access Synthesis of WS2 crystals by the chemical vapor deposition (CVD) method on a SiO2 substrate(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Shaikenova, Altynay; Beissenov, Renat; Muratov, DaurenThe synthesis and characterization of WS2 single crystals grown by chemical vapor deposition (CVD) method thru sulfurization of tungsten oxide thin layer on quartz substrate was studied. Synthesis of WS2 was carried out at 800-1000 °C in CVD system. The sulphur vapor is transported by argon gas (500 sccm). Obtained WS2 single crystals characterized by optical microscope, Raman and photoluminescence analysis. Optical microscope analysis demonstrated that triangular WS2 domains with single phase crystal structure are formed. The thickness of WS2 is 6 layers, which determined by Raman spectroscopy. Photoluminescence spectroscopy is shown on Fig. 20, which revealed a strong peak between 600-660 nm, typically for a monolayer WS2 crystal, where the band gap is equal to 1.96 eV.Item Open Access Efficiency of carbon layer growth in Li4Ti5O12/C composites studied by XPS and Raman spectroscopy(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Pelegov, D. V.; Koshkina, A. A.; Pryakhina, V. I.; Slautin, B. N.; Gorshkov, V. S.The understanding of carbon layer formation is very important for core-shell composite electrodes, comprised of a low conductive core (active material) with a thin carbon shell (conductive additive). In this work we analyze the carbon morphology evolution for the two series of Li4Ti5O12/C samples with carbon content increasing from 0.9 to 5.6 wt%.Item Open Access Autonomous power supply and system enclosure based on hybrid renewable energy sources with wireless communications(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Yapiyev, Vadim; Novokhatskiy, Vladimir; Sagintayev, ZhanayA system solution (Thermobox) for autonomous power supply protection from elements and built-in telemetry was developed for installation of an automatic weather station (AWS) in a remote location with no grid power and housing available.Item Open Access Microstructure Clustering in Multiphase Materials: The role of dimensionless temperature and surface fraction(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Sumbekova, Sholpan; Tsiantis, A.; Papathanasiou, T.D.The significant development and intensified use of composite materials (reinforced plastics, extruded materials and mechanically blended thermoplastics) over the last 30 years has provided the impetus for intense research on their processability as well as on the durability and properties of the final products. In disperse multiphase systems, the dispersion/distribution of particles (microstructure) is regarded as a key factor, both affected by processing and in its turn determining performance.Item Open Access Extraction of phosphorus from sewage sludge ash by CO2 blowing method(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Toyama, TakeshiPhosphorus is an important element not only for use in fertilizers, but also for the manufacture of industrial products. However, depletion of this resource is a problem. Japan relies on imports for the entire amount of phosphorus it consumes. For this reason, there is an urgent need to secure a stable supply of phosphorus. On the ohter hand, there is waste containg a considerable amount of phosphorus. On of them is sewage sludg ash, but it also contains many heavy metals, extraction of only phosphorus is difficult.Item Open Access Quantum-chemical simulation of N-doped Co3O4(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Kaptagay, G.; Mastrikov, Yu.; Kotomin, E.; Sandibaeva, N.; Kopenbaeva, A.; Baitasheva, G.Calculations were performed using the DFT method as implemented in the computer code VASP 5.4[1]. Core electrons were substituted with the US potentials with the PAW method [2]. Exchange-correlation described by the PBE functional [3]. The Hubbard correction U-J=3eV [4] was applied to d-electrons of Cotet as well as Cooct atoms [5]. For defects modeling cubic 56-atom supercell model has been used. For Brillouine zone [6] was sampled with the 2x2x2 Monkhorst- Pack scheme.Item Open Access Nano-structures Embedded Perovskite Solar Cells(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Lee, Heon; Oh, Kyoungsuk; Byun, Minseop; Huh, Daehong; Kim, Minjin; Jo, Yimhyun; Kim, Dong Suk; Ahn, Jinho; Choi, RinoOrganic-inorganic hybrid perovskite solar cells (PSCs) are now attracting tremendous attention for new-generation photovoltaic device because of their excellent power conversion efficiency (PCE) and simple fabrication process. Various researches have been carried out to increase the efficiency of PSCs. Herein, we report on the three methods for enhanced performances of PSCs based on nanoimprint lithography technology.Item Open Access Oxidation of copper nanotubes embedded in the PET template(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Turapbay, Kaysar; Mashentseva, Anastasiya; Temir, Adilet; Kozlovskiy, Artem; Seytbayev, AibekCopper oxide based nanostructures possess excellent physical and chemical properties and has many practical applications such as an medicine, sensors, catalysis, solar cell technology and photovoltaic as well as nanoelectronic. Different approaches have been used to synthesize CuO nanostructures: thermal oxidation of copper, hydrothermal route, aqueous reaction, vapor-liquid-solid synthesis, solution-liquid-solid synthesis as well as physical methods such as laser ablation, arc discharge, precursor thermal decomposition, electron beam lithography, and template-assisted synthesis. However, all these methods require high temperatures, complicated equipment or long reaction time.Item Open Access Methodology of Corrosion Testing of Nuclear and Fusion Reactors’ Materals Using TGA/DSC and MS Complex Techniques(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Tulubayev, Yevgeniy; Bochkov, Vadim; Skakov, M.; Chikhray, Y.; Gordienko, Yuriy; Ponkratov, Yuriy; Kulsartov, Timur; Zaurbekova, Zhanna; Samarkhanov, Kuanysh; Askerbekov, S.Nowadays, nuclear power is the best that humanity has for the production and supply for cheap electric and thermal energy. The development of nuclear power takes place in a rigid competitive struggle, both with the traditional technologies of electricity production, and with alternative (renewable) sources.Item Open Access Development of a quasi-solid composite electrolyte for 3D-structured batteries(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems, 2018-08-08) Munakata, Hirokazu; Shibata, Yoshiyuki; Kanamura, KiyoshiThe development of lithium-ion batteries has been carried out in a layer-by-layer configuration, in which an electrolyte layer is sandwiched with anode and cathode layers.Item Open Access High-performance, heteroepitaxial, nanolaminate device layers on single-crystal-like, artificial substrates and controlled self-assembly of anostructures within device layers for wide-ranging electrical and electronic applications(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems, 2018-08-08) Goyal, AmitFor many energy and electronic applications, single-crystal-like materials offer the best performance. However, in almost all cases, fabrication of single-crystal form of the relevant material is too expensive. In addition, for many applications, very long or wide materials are required a regime not accessible by conventional single-crystal growth.Item Open Access Definition of terms of reference mean power satellites power system(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Altynai, Zauytbek; Uatayev, Nursultan; Abdrakhman, Olzhas; Rakishev, Zhumazhan; Seitjan, YessengaliThe article presents the work of the definition and justification of the terms of reference for the medium-power satellites power system. Byorbital sequence diagram, technical engineering requirements of the selected block. Calculated energy components for resource sources.The term of active work of a spacecraft is provided by the energy needs of its payload with all its on-board systemsItem Open Access The efficiency of depressor additives application for ARPD inhibition and removal in oil storage tanks(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Abdikalykov, Yerlan; Abilmagzhanov A., Arlan; Ivanov, NikolayThe oil produced in the fields of Kazakhstan is characterized by a high content of paraffin hydrocarbons, which is one of the factors forming asphalt-resin-paraffin deposits (ARPD). Rapid formation of ARPD on the inner surface of the oilfield and refinery equipment greatly reduces the efficiency of the pumping installations, impairs the capacity of pipelines and reduces turnaround time equipment operation [1]....Item Open Access A multi-scale model for Transport and Reaction in Heterogeneous Porous Media(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Dobri, Adam; Zeinula, Aizhan; Papathanasiou, T.D.Many practical problems in engineering occur over time and length scales that differ by many orders of magnitude. This makes the application of direct numerical approaches for the prediction of their response impractical. One such class of systems involves heterogeneous porous media in which small spherical porous particles are dispersed within a larger porous domain. We are interested in investigating such systems in which diffusional and convective transport in the continuous phase are coupled with diffusion and reaction/immobilization within the micro-scale inclusions; we develop multi-scale models which enable the prediction of the transient response of such systems taking into account, in a rigorous manner, the transport and reaction at the micro-scale. Immobilized bioreactors [1], ground-water or hydrocarbon flow in fractured rock [2] and ion diffusion in Li-ion batteries [3] are all potential systems of interest.Item Open Access Titanium Based Catalyst Systems for Photo-catalytic CO2 Reduction(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Baimyrza, Aigerim; Balanay, Mannix; Babaa, Moulay-Rachid; Bakenov, ZhumabayThe development of facile and robust photo-catalyst to establish the photo-catalytic CO2 reduction in industrial scale firstly would considerably reduce the amount of greenhouse gases in the atmosphere; secondly, it would found a renewable source of industrially valuable compounds like methanol, formic acid and other hydrocarbon compounds.Item Open Access Improved Performance of LiFe0.25Mn0.75PO4 by using Graphene and Fluorine- Doped Carbon Coating(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Liu, Jian; Sun, Deye; Zhang, Zengqi; Zhang, Li; Jin, YongchengLithium transition metal phosphatesusually need modification of morphology and electron conductivity for improving the electrochemical performance [1,2]. In this work, the electron conductivity of LiFe0.25Mn0.75PO4 is increased by adopting graphene and F-doped carbon.The reductive graphene oxide and F-doped carbon coating LiFe0.25Mn0.75PO4 (LFMP/C-F/rGO) is synthesized by a simple ball milling method.Item Open Access Development of double-layer anode material based on titanium nanotube for lithium batteries(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Ablayeva, K.; Abduakhytova, D; Lepikhin, MRecently, considerable efforts of specialists in the field of power sources are aimed at research on fully 3D microbatteries. The key advantage of a 3D microbattery is the higher surface area as compared to a planar film that allows for increased contact area with the electrolyte and more surface sites available for reversible reactions with lithium ions. This in turn leads to improved battery kinetics and increased power density while maintaining a small areal footprint. This peculiarity of the battery design can be provided by the use of 3D structured cathode/anode materials, the most attractive of which are highly ordered nanotubes (NTs) made of titanium dioxide with high capacity at fast charge and discharge rates and excellent long-term cycling characteristics. Apart from this crucial result, key to the successful fabrication of a full solid state microbattery is the conformal deposition of electrolyte on the self-supported electrode material to preserve the 3D architecture.Item Open Access Preparation of high performance micro- and mesoporous carbon-based sorbents from rice husk and walnut shell(The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”., 2018-08-08) Yeleuov, Muhktar; Smagulova, Gaukhar; Supiyeva, Zhazira; Mansurov, ZulkhairActivated carbon (AC) is a porous substance that is obtained from various carbonaceous materials of organic origin: charcoal, coal coke, rice husk, walnut shell and other materials. AC has a huge number of pores and is characterized by a large surface area per unit mass, as a result of which it has a high adsorption capacity....