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dc.contributor.author | Yussupova, Lyailya![]() |
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dc.date.accessioned | 2024-05-03T13:46:16Z | |
dc.date.available | 2024-05-03T13:46:16Z | |
dc.date.issued | 2024-04-13 | |
dc.identifier.citation | Yussupova L., Hayrapetyan D. (2024). The synthetic study of the aza-annulation reaction of enamines and further decarboxylative modifications. Nazarbayev University School of Sciences and Humanities | en_US |
dc.identifier.uri | http://nur.nu.edu.kz/handle/123456789/7628 | |
dc.description.abstract | Aza-annulation of enamines generated from β-ketoester using maleic and itaconic anhydrides produces functionalized γ- and δ-lactams with good diastereoselectivity. Subsequent hydrolysis of the aza-annulation products yielded dicarboxylic acids, which are susceptible to further decarboxylation. Simultaneous migration of the C=C double bond occurs during the decarboxylation of β-γ unsaturated carboxylic acids with an electron-rich enamide double bond. This provides a straightforward synthesis route towards 1,2,3,4- tetrahydropyridine-2-ones and 3-pyrrolin-2-ones. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Nazarbayev University School of Sciences and Humanities | en_US |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 United States | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/us/ | * |
dc.subject | regioselectivity | en_US |
dc.subject | Type of access: Embargo | en_US |
dc.subject | aza-annulation | en_US |
dc.subject | stereoselectivity | en_US |
dc.subject | decarboxylation | en_US |
dc.title | The synthetic study of the aza-annulation reaction of enamines and further decarbTHE SYNTHETIC STUDY OF THE AZA-ANNULATION REACTION OF ENAMINES AND FURTHER DECARBOXYLATIVE MODIFICATIONSoxylative modifications | en_US |
dc.type | Bachelor's thesis | en_US |
workflow.import.source | science |
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