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dc.contributor.author | Peng, Huifen | |
dc.contributor.author | Wang, Xiaoran | |
dc.contributor.author | Zhao, Yan | |
dc.contributor.author | Tan, Taizhe | |
dc.contributor.author | Bakenov, Zhumabay | |
dc.contributor.author | Zhang, Yongguang | |
dc.date.accessioned | 2018-11-09T08:20:06Z | |
dc.date.available | 2018-11-09T08:20:06Z | |
dc.date.issued | 2018-04 | |
dc.identifier.citation | Huifen Peng, Xiaoran Wang, Yan Zhao, Taizhe Tan, Zhumabay Bakenov and Yongguang Zhang. Synthesis of a Flexible Freestanding Sulfur/Polyacrylonitrile/Graphene Oxide as the Cathode for Lithium/Sulfur Batteries. 2018. Polymers | en_US |
dc.identifier.uri | http://nur.nu.edu.kz/handle/123456789/3616 | |
dc.description.abstract | Rechargeable lithium/sulfur (Li/S) batteries have received quite significant attention over the years because of their high theoretical specific capacity (1672 mAh g1) and energy density (2600 mAh g1) which has led to more efforts for improvement in their electrochemical performance. Herein, the synthesis of a flexible freestanding sulfur/polyacrylonitrile/graphene oxide (S/PAN/GO) as the cathode for Li/S batteries by simple method via vacuum filtration is reported. The S/PAN/GO hybrid binder-free electrode is considered as one of the most promising cathodes for Li/S batteries. Graphene oxide (GO) slice structure provides effective ion conductivity channels and increases structural stability of the ternary system, resulting in excellent electrochemical properties of the freestanding S/PAN/GO cathode. Additionally, graphene oxide (GO) membrane was able to minimize the polysulfides’ dissolution and their shuttle, which was attributed to the electrostatic interactions between the negatively-charged species and the oxygen functional groups on GO. Furthermore, these oxygen-containing functional groups including carboxyl, epoxide and hydroxyl groups provide active sites for coordination with inorganic materials (such as sulfur). It exhibits the initial reversible specific capacity of 1379 mAh g1 at a constant current rate of 0.2 C and maintains 1205 mAh g1 over 100 cycles (~87% retention). In addition, the freestanding S/PAN/GO cathode displays excellent coulombic efficiency (~100%) and rate capability, delivering up to 685 mAh g1 capacity at 2 C | en_US |
dc.language.iso | en | en_US |
dc.publisher | Polymers | en_US |
dc.rights | Attribution-NonCommercial-ShareAlike 3.0 United States | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/us/ | * |
dc.subject | lithium | en_US |
dc.subject | sulfur battery | en_US |
dc.subject | sulfur | en_US |
dc.subject | polyacrylonitrile | en_US |
dc.subject | graphene oxide | en_US |
dc.subject | freestanding cathode | en_US |
dc.title | Synthesis of a Flexible Freestanding Sulfur/Polyacrylonitrile/Graphene Oxide as the Cathode for Lithium/Sulfur Batteries | en_US |
dc.type | Article | en_US |
workflow.import.source | science |
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