Аннотации:
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses
a variety of hydroboration reactions, including the first example
of catalytic addition of HBCat to nitriles to form the
bis(borylated) amines RCH2N(BCat)2. The latter species easily
undergoes chemoselective coupling with aldehydes R0C(O)H to
yield imines RCH2NQC(H)R0