Multiple coupling of silanes with imido complexes of Mo
| dc.contributor.author | Khalimon, Andrey | |
| dc.contributor.author | McLeod, Nicolas A. | |
| dc.contributor.author | Ignatov, Stanislav K. | |
| dc.contributor.author | Okhapkin, Andrey I. | |
| dc.contributor.author | Kuzmina, Lyudmila G. | |
| dc.contributor.author | Howardd, Judith A. K. | |
| dc.contributor.author | Nikonov, Georgii I. | |
| dc.date.accessioned | 2016-02-08T04:20:05Z | |
| dc.date.available | 2016-02-08T04:20:05Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | The bis(imido) complexes (tBuNv)2Mo(PMe3)(L) (L = PMe3, C2H4) react with up to three equivalents of silane PhSiH3 to give the imido-bridged disilyl silyl Mo(VI) complex (tBuN){μ-tBuN(SiHPh)2}Mo(H)(SiH2Ph)- (PMe3)2 (3) studied by NMR, IR and X-ray diffraction. NMR data supported by DFT calculations show that complex 3 is an unusual example of a silyl hydride of Mo(VI), without significant Si⋯H interaction. Mechanistic NMR studies revealed that silane addition proceeds in a stepwise manner via a series of Si–H⋯M agostic and silanimine complexes whose structures were further elucidated by DFT calculations | ru_RU |
| dc.identifier.citation | Andrey Y. Khalimon, Nicolas A. McLeod, Stanislav K. Ignatov, Andrey I. Okhapkin, Lyudmila G. Kuzmina, Judith A. K. Howardd, Georgii I. Nikonov; 2014; Multiple coupling of silanes with imido complexes of Mo; Dalton Transactions | ru_RU |
| dc.identifier.uri | http://nur.nu.edu.kz/handle/123456789/1162 | |
| dc.language.iso | en | ru_RU |
| dc.rights | Attribution-NonCommercial-ShareAlike 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/us/ | * |
| dc.subject | Research Subject Categories::NATURAL SCIENCES::Chemistry | ru_RU |
| dc.subject | silanes | ru_RU |
| dc.title | Multiple coupling of silanes with imido complexes of Mo | ru_RU |
| dc.type | Article | ru_RU |