Imido–hydrido complexes of Mo(IV): catalysis and mechanistic aspects of hydroboration reactions
| dc.contributor.author | Khalimon, Andrey | |
| dc.contributor.author | Farhaa, Philip M. | |
| dc.contributor.author | Nikonov, Georgii I. | |
| dc.date.accessioned | 2016-02-08T04:31:51Z | |
| dc.date.available | 2016-02-08T04:31:51Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | Imido–hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl) catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to nitriles to form bis(borylated) amines RCH2N(BCat)2. Stoichiometric reactivity of complexes 1 and 2 with nitriles and HBCat suggest that catalytic reactions proceed via a series of agostic borylamido and borylamino complexes. For complex 1, catalysis starts with addition of nitriles across the Mo–H bond to give (ArN)Mo(Cl)(NvCHR)(PMe3)2; whereas for complex 2 stoichiometric reactions suggest initial addition of HBCat to form the agostic complex Mo(H)2(PMe3)3(η3-NAr-HBcat) | ru_RU |
| dc.identifier.citation | Andrey Y. Khalimon, Philip M. Farhaa, Georgii I. Nikonov; 2015; Imido–hydrido complexes of Mo(IV): catalysis and mechanistic aspects of hydroboration reactions; Dalton Transactions | ru_RU |
| dc.identifier.uri | http://nur.nu.edu.kz/handle/123456789/1163 | |
| dc.language.iso | en | ru_RU |
| dc.rights | Attribution-NonCommercial-ShareAlike 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/us/ | * |
| dc.subject | Research Subject Categories::NATURAL SCIENCES::Chemistry | ru_RU |
| dc.subject | Imido–hydrido complexes of Mo(IV) | ru_RU |
| dc.title | Imido–hydrido complexes of Mo(IV): catalysis and mechanistic aspects of hydroboration reactions | ru_RU |
| dc.type | Article | ru_RU |