Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategy

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dc.contributor.authorKaipov, Almaz
dc.contributor.authorHayrapetyan, Davit
dc.date.accessioned2024-05-04T07:30:36Z
dc.date.available2024-05-04T07:30:36Z
dc.date.issued2024-04-13
dc.description.abstractIn search for developing synthetic routes towards spirocyclic morpholines and tetrahydrofurans, we developed a convenient electrochemical protocol for dearomatization of methoxy-benzene derivatives. The electrochemical oxidation of the electron-rich benzene ring followed by intramolecular capture of the cation-radical intermediates accessed desired spirocyclic products. The scope of the reaction demonstrated tolerance of various functional groups such as alkenes, alcohols, bromines, fluorines, trifuoromethyl, cyano, ester and amides with reaction yield varying between 46-91%.en_US
dc.identifier.citationKaipov, A. Hayrapetyan, D. (2024) Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategyen_US
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/7637
dc.language.isoen_USen_US
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/us/*
dc.subjectElectrochemical organic synthesisen_US
dc.subjectOxidative dearomatizationen_US
dc.titleElectrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategyen_US
dc.typeBachelor's thesisen_US
workflow.import.sourcescience

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