Catalytic hydroboration by an imido-hydrido complex of Mo(IV)
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Khalimon, Andrey
Farha, Philip
Kuzmina, Lyudmila G.
Nikonov, Georgii I.
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Abstract
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses
a variety of hydroboration reactions, including the first example
of catalytic addition of HBCat to nitriles to form the
bis(borylated) amines RCH2N(BCat)2. The latter species easily
undergoes chemoselective coupling with aldehydes R0C(O)H to
yield imines RCH2NQC(H)R0
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Andrey Y. Khalimon, Philip Farha, Lyudmila G. Kuzminab, Georgii I. Nikonov; 2011; Catalytic hydroboration by an imido-hydrido complex of Mo(IV); Chemical Communications
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