A green chemical method for synthesis of bromine-containing “building blocks” for the production of photovoltaic polymers

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dc.contributor.authorKhrustalev, D.
dc.contributor.authorYedrissov, A.
dc.contributor.authorShishlova, Y.
dc.contributor.authorTyagunova, O.
dc.contributor.authorIlyassov, B.
dc.contributor.authorKurbanova, A.
dc.date.accessioned2018-09-05T11:38:08Z
dc.date.available2018-09-05T11:38:08Z
dc.date.issued2018-08-08
dc.description.abstractBromine-containing derivatives of aromatic and heteroaromatic compounds are the most important "building blocks" in the assembly of modern Photovoltaic Polymers (PV). While PV is being developed to produce "green" energy, converting sunlight to electricity, the reactions for producing brominated derivatives of building blocks described in the literature are examples of obsolete and environmentally dirty technologies. More environmentally harmful than bromination with molecular bromine [1] can only be bromination by molecular bromine in a concentrated hydrobromic acid medium [2]. Using 1,1'-diphenyl (1), 9H-diphenylcarbazole (2) and thiophene (3) as examples, we successfully tested the bromination of the above objects with a mixture of potassium bromide and bromate in acetic acid as outlined in the diagram.en_US
dc.identifier.citationKhrustalev, D. et al. (2018) A green chemical method for synthesis of bromine-containing “building blocks” for the production of photovoltaic polymers. The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”. p61.en_US
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/3479
dc.language.isoenen_US
dc.publisherThe 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”.en_US
dc.rightsAttribution-NonCommercial-ShareAlike 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/us/*
dc.subject"green" energyen_US
dc.subjectelectricityen_US
dc.subjectGreen Chemistryen_US
dc.titleA green chemical method for synthesis of bromine-containing “building blocks” for the production of photovoltaic polymersen_US
dc.typeAbstracten_US
workflow.import.sourcescience

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