Synthesis and anodic electrochemistry of cymanquine and related complexes

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dc.contributor.authorLam, Kevin
dc.contributor.authorGeiger, William E.
dc.creatorKevin, Lam
dc.date.accessioned2017-12-20T03:38:40Z
dc.date.available2017-12-20T03:38:40Z
dc.date.issued2016-08-15
dc.description.abstractAbstract Three compounds have been prepared in which a 4-aminochloroquinoline moiety is covalently linked to a cyclopentadienyl manganese tricarbonyl moiety. One of these (“cymanquine”, 4) is the analogue of the potent antimalarial drug ferroquine in which an FeCp group has been replaced by a Mn(CO)3 group. The anodic electrochemistry of the new compounds was investigated in dichloromethane, using [NBu4][B(C6F5)4] as the supporting electrolyte. Compared to ferroquine, oxidations of the new compounds occur at considerably more positive potentials and are highly irreversible, being located at their amine groups rather than at the organometallic center.en_US
dc.identifierDOI:10.1016/j.jorganchem.2016.05.009
dc.identifier.citationKevin Lam, William E. Geiger, Synthesis and anodic electrochemistry of cymanquine and related complexes, In Journal of Organometallic Chemistry, Volume 817, 2016, Pages 15-20en_US
dc.identifier.issn0022328X
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0022328X16301954
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/2957
dc.language.isoenen_US
dc.publisherJournal of Organometallic Chemistryen_US
dc.relation.ispartofJournal of Organometallic Chemistry
dc.rights.license© 2016 Elsevier B.V. All rights reserved.
dc.subjectBioorganometallicen_US
dc.subjectCymantreneen_US
dc.subjectFerroquineen_US
dc.subjectChloroquinolineen_US
dc.subjectAnodic oxidationen_US
dc.subjectWeakly coordinating anionen_US
dc.titleSynthesis and anodic electrochemistry of cymanquine and related complexesen_US
dc.typeArticleen_US
elsevier.aggregationtypeJournal
elsevier.coverdate2016-08-15
elsevier.coverdisplaydate15 August 2016
elsevier.endingpage20
elsevier.identifier.doi10.1016/j.jorganchem.2016.05.009
elsevier.identifier.eid1-s2.0-S0022328X16301954
elsevier.identifier.piiS0022-328X(16)30195-4
elsevier.identifier.scopusid84969583289
elsevier.openaccess0
elsevier.openaccessarticlefalse
elsevier.openarchivearticlefalse
elsevier.startingpage15
elsevier.teaserThree compounds have been prepared in which a 4-aminochloroquinoline moiety is covalently linked to a cyclopentadienyl manganese tricarbonyl moiety. One of these (“cymanquine”, 4) is the analogue of...
elsevier.volume817
workflow.import.sourcescience

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