Novel and Pragmatic Approach to Design Silicon Alloy Anode by Equilibrium Method

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dc.contributor.authorUmirov, Nurzhan
dc.contributor.authorSeo, Deok-Ho
dc.contributor.authorKim, Hyang-Yeon
dc.contributor.authorKim, Sung-Soo
dc.date.accessioned2020-09-23T05:48:14Z
dc.date.available2020-09-23T05:48:14Z
dc.date.issued2020-08
dc.description.abstractSilicon is honored as one of the most promising anode materials for Lithium-ion Batteries (LIBs) because of its high theoretical specific capacity (4200 mAh/g) compared to commercially available graphite anodes (370 mAh/g). Over 20 years, Si has been intensively investigated due to considerable volume expansion of up to 300% upon electrochemical lithiation, leading to electrode cracking and rapid capacity fading. Numerous strategies have been reported with excellent cycle performances in lab-scale [1]. However, up today, many material manufacturers and start-up companies failed to scale-up those technologies for mass-production, in particular, due to the lack of reproducibility, economical feasibility, etc. Herein, we demonstrate a novel and pragmatic approach for the mass-producible synthesis of Si-alloys with homogeneous microstructure and improved electrochemical performances. Namely, we have designed and optimized amorphous phase Si-alloy composition using reliable and mass-producible melt-spinning process (Fig.1). Further, amorphous alloy is subjected to the thermal annealing process to size-controllable re-crystallization and homogeneous growth of nano-Si grains in inactive matrix. As a result of breakthrough strategy the Si-alloy electrode delivered a high specific capacity of 900 mAh/g for 100 cycles at 0.1 A/g with nearly 99% capacity retention [2].en_US
dc.identifier.citationUmirov, N., Seo, D., Kim, H., & Kim, S. (2020). Novel and Pragmatic Approach to Design Silicon Alloy Anode by Equilibrium Method [Abstract]. The 8th International Conference on Nanomaterials and Advanced Energy Storage Systems; Nazarbayev University; National Laboratory Astana; Institute of Batteries.
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/4982
dc.language.isoenen_US
dc.publisherThe 8th International Conference on Nanomaterials and Advanced Energy Storage Systems; Nazarbayev University; National Laboratory Astana; Institute of Batteriesen_US
dc.rightsAttribution-NonCommercial-ShareAlike 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/us/*
dc.subjectResearch Subject Categories::TECHNOLOGYen_US
dc.subjectanode materialsen_US
dc.subjectLithium-ion Batteriesen_US
dc.subjectLIBsen_US
dc.subjecthigh theoretical specific capacityen_US
dc.subjectgraphite anodesen_US
dc.titleNovel and Pragmatic Approach to Design Silicon Alloy Anode by Equilibrium Methoden_US
dc.typeAbstracten_US
workflow.import.sourcescience

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