Crystal structure of 5,15-bis-(4-methyl-phen-yl)-10,20-bis-(4-nitro-phen-yl)porphyrin nitro-benzene disolvate

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dc.contributor.authorBaptayev, Bakhytzhan
dc.contributor.authorAdilov, Salimgerey
dc.date.accessioned2019-11-05T05:16:58Z
dc.date.available2019-11-05T05:16:58Z
dc.date.issued2018-01-01
dc.description.abstractThe whole mol-ecule of the title porphyrin, C46H32N6O4·2C6H5NO2, which crystallized as a nitro-benzene disolvate, is generated by inversion symmetry. The porphyrin macrocycle is almost planar, the maximum deviation from the mean plane of the non-hydrogen atoms is 0.097 (2) Å. The aryl rings at the meso positions are inclined to this mean plane by 74.84 (6)° for the nitro-phenyl rings and 73.37 (7)° for the tolyl rings. In the crystal, the porphyrin mol-ecules are linked by C-H⋯O hydrogen bonds, forming chains along [100]. The solvent mol-ecules are also linked by C-H⋯O hydrogen bonds, forming chains along [100]. Inter-digitation of the p-tolyl groups along the c axis creates rectangular channels in which the solvent mol-ecules are located.en_US
dc.identifier.citationBaptayev, B., & Adilov, S. (2018). Crystal structure of 5,15-bis-(4-methyl-phen-yl)-10,20-bis-(4-nitro-phen-yl)porphyrin nitro-benzene disolvate. Acta Crystallographica Section E: Crystallographic Communications, 74(Pt 1), 55-58. https://doi.org/10.1107/S2056989017017868en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989017017868
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/4289
dc.language.isoenen_US
dc.publisherNazarbayev University School of Sciences and Humanitiesen_US
dc.rightsAttribution-NonCommercial-ShareAlike 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/us/*
dc.titleCrystal structure of 5,15-bis-(4-methyl-phen-yl)-10,20-bis-(4-nitro-phen-yl)porphyrin nitro-benzene disolvateen_US
dc.typeArticleen_US
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