Photo Lewis acid generators: photorelease of B(C6F5)3 and applications to catalysis

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dc.contributor.authorKhalimon, Andrey
dc.contributor.authorShaw, Bryan K.
dc.contributor.authorMarwitz, Adam J. V.
dc.contributor.authorPiers, Warren E.
dc.contributor.authorBlackwellc, James M.
dc.contributor.authorParveza, Masood
dc.contributor.institutionSchool of Sciences and Humanities
dc.date.accessioned2016-02-08T04:41:42Z
dc.date.available2016-02-08T04:41:42Z
dc.date.issued2015
dc.description.abstractA series of molecules capable of releasing of the strong organometallic Lewis acid B(C6F5)3 upon exposure to 254 nm light have been developed. These photo Lewis acid generators (PhLAGs) can now serve as photoinitiators for several important B(C6F5)3-catalyzed reactions. Herein is described the synthesis of the triphenylsulfonium and diphenyliodonium salts of carbamato- and hydridoborates, their establishment as PhLAGs, and studies aimed at defining the mechanism of borane release. Factors affecting these photolytic reactions and the application of this concept to photoinduced hydrosilylation reactions and construction of siloxane scaffolds are also discussed
dc.identifier.citationKhalimon, A. Y., Shaw, B. K., Marwitz, A. J., Piers, W. E., Blackwell, J. M., & Parvez, M. (2015). Photo Lewis acid generators: photorelease of B (C6F5) 3 and applications to catalysis. Dalton Transactions, 44(41), 18196-18206.
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/1164
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.rightsAttribution 3.0 United States
dc.sourceDalton Transactions, 44(41), 18196-18206.
dc.subjectChemistry
dc.subjectPhoto Lewis acid generators
dc.titlePhoto Lewis acid generators: photorelease of B(C6F5)3 and applications to catalysis
dc.typeArticle

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