PREPARATION OF A NI3SN2 ALLOY-TYPE ANODE EMBEDDED IN CARBON NANOFIBERS BY ELECTROSPINNING FOR LITHIUM-ION BATTERIES
| dc.contributor.author | Ibadulla, Nurbol | |
| dc.contributor.author | Belgibayeva, Ayaulym | |
| dc.contributor.author | Nurpeissova, Arailym | |
| dc.contributor.author | Bakenov, Zhumabay | |
| dc.contributor.author | Kalimuldina, Gulnur | |
| dc.date.accessioned | 2023-03-27T06:09:17Z | |
| dc.date.available | 2023-03-27T06:09:17Z | |
| dc.date.issued | 2022 | |
| dc.description.abstract | A pure-phase Ni3Sn2 intermetallic alloy encapsulated in a carbon nanofiber matrix (Ni3Sn2@CNF) was successfully prepared by electrospinning and applied as anode for lithium-ion batteries. The physical and electrochemical properties of the Ni3Sn2@CNF were compared to that of pure CNF. The resultant Ni3Sn2@CNF anode produced a high initial discharge capacity of ∼1300 mA h g−1, later stabilizing and retaining ∼350 mA h g−1 (vs. 133 mA h g−1 for CNF) after 100 cycles at 0.1C. Furthermore, even at a high current density of 1C, it delivered a high initial discharge capacity of ∼1000 mA h g−1, retaining ∼313 mA h g−1 (vs. 66 mA h g−1 for CNF) at the 200th cycle. The superior electrochemical properties of the Ni3Sn2@CNF over CNF were attributed to the presence of electrochemically active Sn and decreased charge-transfer resistance with the alloy encapsulation, as confirmed from cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) results. Finally, post-mortem field-emission scanning electron microscopy (FE-SEM) images proved the preservation of the carbon nanofibers and the alloy after cycling, confirming the successful accommodation of the volume changes during the alloying/dealloying reactions of Sn in the Ni3Sn2@CNF. | en_US |
| dc.identifier.citation | Ibadulla, N., Belgibayeva, A., Nurpeissova, A., Bakenov, Z., & Kalimuldina, G. (2022). Preparation of a Ni3Sn2 alloy-type anode embedded in carbon nanofibers by electrospinning for lithium-ion batteries. RSC Advances, 12(43), 27899–27906. https://doi.org/10.1039/d2ra05734d | en_US |
| dc.identifier.uri | http://nur.nu.edu.kz/handle/123456789/6976 | |
| dc.language.iso | en | en_US |
| dc.publisher | RSC Advances | en_US |
| dc.rights | Attribution-NonCommercial-ShareAlike 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/us/ | * |
| dc.subject | Type of access: Open Access | en_US |
| dc.subject | Ni3Sn2 alloy-type anode | en_US |
| dc.subject | lithium-ion batteries | en_US |
| dc.title | PREPARATION OF A NI3SN2 ALLOY-TYPE ANODE EMBEDDED IN CARBON NANOFIBERS BY ELECTROSPINNING FOR LITHIUM-ION BATTERIES | en_US |
| dc.type | Article | en_US |
| workflow.import.source | science |