Na3V(PO3)3N: New zero-strain and 4V cathode material for Na-ion batteries

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Date

2018-08-08

Authors

Kim, Jongsoon

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Publisher

The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”.

Abstract

These We developed Na3V(PO3)3N as a novel 4V-class and zero-strain cathode material for Na-ion batteries. Through the combined studies using neutron and X-ray diffraction, it was identified that the Na3V(PO3)3N contains 3-dimensional channels, which enables the facile Na diffusion in the structure. The Na (de)intercalation of Na3V(PO3)3N was occur at ~4 V (vs. Na/Na+) via the V3+/V4+ redox reaction and its capacity retention over 3000 cycles was ~67% of the initial capacity.

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Keywords

Cathode Materials

Citation

Kim, Jongsoon. (2018) Na3V(PO3)3N: New zero-strain and 4V cathode material for Na-ion batteries. The 6th International Conference on Nanomaterials and Advanced Energy Storage Systems. Institute of Batteries LLP, Nazarbayev University, and PI “National Laboratory Astana”. p18.

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