Browsing by Author "Geiger, William E."

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Corrigendum to “Synthesis and anodic electrochemistry of cymanquine and related complexes” [J. Organomet. Chem. 817 (15 August 2016) 15–20]

Lam, Kevin; Geiger, William E. (Journal of Organometallic Chemistry, 2017-05-15)

The authors regret that the oxidation potentials given for compound 5 in the paper are incorrect. The correct values, referenced to ferrocene, are 0.88 V for the first oxidation and 1.14 V for the second oxidation.
One-electron oxidation of chloroquine, cymanquine, and related aminoquinolines in nonaqueous media

Lam, Kevin; Van Wyck, Stephen J.; Geiger, William E. (Journal of Electroanalytical Chemistry, 2017-08-15)

Abstract The anodic oxidation of a series of secondary-amine-substituted chloroquinoline derivatives, 1–5, has been studied in dichloromethane/0.05M [NBu4][B(C6F5)4]. Compounds 4 and 5 contain organometallic moieties of ...
Synthesis and anodic electrochemistry of cymanquine and related complexes

Lam, Kevin; Geiger, William E. (Journal of Organometallic Chemistry, 2016-08-15)

Abstract Three compounds have been prepared in which a 4-aminochloroquinoline moiety is covalently linked to a cyclopentadienyl manganese tricarbonyl moiety. One of these (“cymanquine”, 4) is the analogue of the potent ...