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Item Open Access Excited States of Positronic Lithium and Beryllium(2013) Bubin, Sergiy; Prezhdo, Oleg V.Using a variational method with an explicitly correlated Gaussian basis, we study the eþ-Li and eþ-Be complexes in the ground and lowest excited states with higher spin multiplicity. Our calculations provide rigorous theoretical confirmation that a positron can be attached to the excited states: 1s2s2p 4Po and 1s22s2p 3Po for eþ-Li and eþ-Be, respectively. The result is particularly notable for the eþ-Be complex, as the excited 3Po state lies below the autoionization threshold. We report accurate binding energies, annihilation rates and structural properties of these positron-atom systems. The existence of the ground and metastable excited states with bound positron opens up a new route to the presently lacking experimental verification of stability of a positron binding to any neutral atom