The 8th International Conference on Nanomaterials and Advanced Energy Storage Systems
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Browsing The 8th International Conference on Nanomaterials and Advanced Energy Storage Systems by Subject "aluminum foil"
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Item Open Access Analysis of the dependence of the structural parameters of membranes based on NOA and anode current on the parameters of the production process(The 8th International Conference on Nanomaterials and Advanced Energy Storage Systems; Nazarbayev University; National Laboratory Astana; Institute of Batteries, 2020-08) Batalova, M.S.; Alpysbayeva, B.E.; Korobova, N.E.Among the porous membranes, PAOA-based membranes, formed by the method of electrochemical anodizing of aluminum foil, are of the greatest interest. Membranes obtained by electrochemical anodization are highly ordered structures with parallel vertical pores [1]. The unique porous structure, the parameters (diameter, length and distance between adjacent pores) of which can be varied during the synthesis process allows the use of films of porous aluminum oxide as inorganic membranes, templating material for the synthesis of nanowires or nanotubes with a controlled diameter and high geometric anisotropy, as well as 2D photonic crystals and biosensors [2,3]. Aluminum foil (99.999%) with a thickness of 0.5 mm was used as the starting material for the synthesis of films of porous aluminum oxide. Oxide layer formed on the foil surface was removed by electrochemical polishing of aluminum in a mixture of 40g CrO3 + 210 ml H3PO4 (concentrated acid) + 45 ml H2O at a temperature of 80°C. The membranes based on porous alumina were obtained by a two-stage anodizing process in 0.4 M oxalic acid at a temperature of 4–19 ° C. With an increase in the magnitude of the voltage, the thickness of the porous film, which grows in the same time, increases; the growth rate of the film grows sublinearly. With increasing voltage value, the initial value of the anode current also increases. The anode current in the anodization process gradually decreases, which, as already noted, indicates the beginning of pore formation and further stabilization of the anode current occurs when the pores grow deep into the oxide film. According to the data obtained on the dependence of the anode current on the time of the anodization process, it can be concluded that the maximum current value at room temperature is higher than at low temperature, and this can be traced for all voltage values.Item Open Access Etching the surface of aluminum foil using high-frequency plasma to produce a nanoporous aluminum oxide membrane(The 8th International Conference on Nanomaterials and Advanced Energy Storage Systems; Nazarbayev University; National Laboratory Astana; Institute of Batteries, 2020-08) Amirbekova, G.S.; Alpysbayeva, B.E.; Erlanuly, E.; Gabdullin, M. T.; Smirnov, V.Y.In recent years, the trend of creating and improving sensitive sensors has taken an important place in the field of medicine, environmental monitoring and research of biomolecular interactions. In addition, these nanoporous aluminum oxide films are actively studied in the fields of nanoelectronics, microbiology, and nuclear physics [1]. In this research work, a porous aluminum oxide membrane with pre-treatment of the aluminum coating with plasma was developed for the first time. The process of processing the aluminum film with plasma in a high-frequency discharge, in a vacuum environment, and as a result, the surface oxide layer was destroyed and a surface roughness was formed. During the experiment, a vacuum medium with a Vup-5 device was adopted, a plasma with a pink tinge of 0.6-0.7 Pa was formed between the two electrodes, argon gas was obtained as the main gas, and room temperature was used as the temperature parameter. In order to determine the differences that occur on the surface of the film, the power size was obtained to such a different extent. And the processing time for all films is the same value t=15 minutes. The process of electrochemical anodizing into an aluminum film with this surface treated with plasma was also carried out. As the electrolyte, orthophosphor was obtained, the chemical reaction took place at room temperature 190C, voltage U=80 V, t=30 min. The process of electrochemical anodizing was a step-by-step process. In the experiment in vacuum environment, in a high-frequency discharge plasma treated surface layer of the aluminum film, based on the electrochemical anodization received nanoporous aluminium oxide. In the course of the study, it was noted that the change in parameters, in particular, differs from the surface roughness due to the different power values of 20 W 50 W and 70 W (Fig. 1).