Molkenova, A.Belgibayeva, A.Ibrayeva, D.Sultanov, M.Zhumagali, S.Akhmetova, N.Hara, T.Bakenov, Z.2017-12-152017-12-152017-01-01A. Molkenova, A. Belgibayeva, D. Ibrayeva, M. Sultanov, S. Zhumagali, N. Akhmetova, T. Hara, Z. Bakenov, A new step in the development of Zn/LiFePO4 aqueous battery, In Materials Today: Proceedings, Volume 4, Issue 3, Part A, 2017, Pages 4452-445722147853https://www.sciencedirect.com/science/article/pii/S2214785317305643http://nur.nu.edu.kz/handle/123456789/2916Abstract In recent years, aqueous batteries have gained much attention due to their low production cost and exceptional safety compared to commercial Li-ion battery systems. Three-dimensional (3D) structure could be promising to enhance these batteries energy capacity. In this work, the electrochemical performance of 3D Zn electrode, developed for aqueous rechargeable Zn/LiFePO4 (Zn/LFP) battery system, was studied. Formation of uniformly coated Zn metal on the three-dimensionally organized carbon fibers was verified by field emission scanning electron microscopy (FE-SEM). The electrochemical performance of the battery with this anode was tested for over 50 cycles, where the initial capacity decayed by 11%. Further, poly(methyl methacrylate) (PMMA) and poly(p-phenylene oxide) (PPO) polymer coatings were extensively investigated as a potential separator for the 3D aqueous battery system. Cyclability of PMMA-coated Zn anode was better than that of “plane” Zn; however, the initial capacity of 3D Zn anode was lower than that for the counterpart system.3D structured electrodeaqueous rechargeable lithium-ion batteryelectrodepositionelectropolymerizationpolymer coatingArticle© 2017 Elsevier Ltd. All rights reserved.