Khalimon, AndreyFarha, PhilipKuzmina, Lyudmila G.Nikonov, Georgii I.2016-02-082016-02-082011Andrey Y. Khalimon, Philip Farha, Lyudmila G. Kuzminab, Georgii I. Nikonov; 2011; Catalytic hydroboration by an imido-hydrido complex of Mo(IV); Chemical Communicationshttp://nur.nu.edu.kz/handle/123456789/1161The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R0C(O)H to yield imines RCH2NQC(H)R0enAttribution-NonCommercial-ShareAlike 3.0 United StatesResearch Subject Categories::NATURAL SCIENCES::Chemistryimido-hydrido complexArticle