Luchinin, NikitaFedotov, Stanislav2022-09-052022-09-052022-08Luchinin, N. Fedotov, S. (2022). KTiPO4F and α-TiPO4 as electrode materials for metal-ion batteries. KTiPO4F and α-TiPO4 as electrode materials for metal-ion batterieshttp://nur.nu.edu.kz/handle/123456789/6614Nowadays, 3d-metal phosphates are considered as promising electrode materials for metal ion batteries (MIB). A phosphate group increases working potential of the Mn+1/Mn+ redox pair and provides higher electrochemical and thermal stability that contribute to a longer life of electrodes up to several thousand charge/discharge cycles. Typically titanium redox transitions are not used for cathode applications because of low operating potential. Among titanium transitions Ti4+/Ti3+ and Ti3+/Ti2+, the latter is supposed to demonstrate a lower working potential which is prefferable for anode materials, however, due to the side conversion reactions, such examples are extremely rare. The d1 electronic configuration of titanium (III) compounds is more preferable due to the higher electronic conductivity. Titanium reagents are comparable in cost with those of manganese, are produced widely and everywhere, non-toxic, and can be easily recycled, making titanium an attractive element for the industryenAttribution-NonCommercial-ShareAlike 3.0 United StatesType of access: EmbargoKTiPO4Fα-TiPO4metal-ion batteriesAbstract