Khalimon, Andrey; Farha, Philip; Kuzmina, Lyudmila G.; Nikonov, Georgii I.(2011)
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses
a variety of hydroboration reactions, including the first example
of catalytic addition of HBCat to nitriles to form the
bis(borylated) amines RCH2N(BCat)2. The ...
Khalimon, Andrey; Farhaa, Philip M.; Nikonov, Georgii I.(2015)
Imido–hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl)
catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to
nitriles to ...
Khalimon, Andrey; McLeod, Nicolas A.; Ignatov, Stanislav K.; Okhapkin, Andrey I.; Kuzmina, Lyudmila G.; Howardd, Judith A. K.; Nikonov, Georgii I.(2014)
The bis(imido) complexes (tBuNv)2Mo(PMe3)(L) (L = PMe3, C2H4) react with up to three equivalents of
silane PhSiH3 to give the imido-bridged disilyl silyl Mo(VI) complex (tBuN){μ-tBuN(SiHPh)2}Mo(H)(SiH2Ph)-
(PMe3)2 (3) ...
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