Khalimon, Andrey; Farha, Philip; Kuzmina, Lyudmila G.; Nikonov, Georgii I.(2011)
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses
a variety of hydroboration reactions, including the first example
of catalytic addition of HBCat to nitriles to form the
bis(borylated) amines RCH2N(BCat)2. The ...
Khalimon, Andrey; Farhaa, Philip M.; Nikonov, Georgii I.(2015)
Imido–hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl)
catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to
nitriles to ...
Khalimon, Andrey; McLeod, Nicolas A.; Ignatov, Stanislav K.; Okhapkin, Andrey I.; Kuzmina, Lyudmila G.; Howardd, Judith A. K.; Nikonov, Georgii I.(2014)
The bis(imido) complexes (tBuNv)2Mo(PMe3)(L) (L = PMe3, C2H4) react with up to three equivalents of
silane PhSiH3 to give the imido-bridged disilyl silyl Mo(VI) complex (tBuN){μ-tBuN(SiHPh)2}Mo(H)(SiH2Ph)-
(PMe3)2 (3) ...
Khalimon, Andrey; Shaw, Bryan K.; Marwitz, Adam J. V.; Piers, Warren E.; Blackwellc, James M.; Parveza, Masood(2015)
A series of molecules capable of releasing of the strong organometallic Lewis acid B(C6F5)3 upon
exposure to 254 nm light have been developed. These photo Lewis acid generators (PhLAGs) can now
serve as photoinitiators ...
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