Abstract:
Using a variational method with an explicitly correlated Gaussian basis, we study the eþ-Li and eþ-Be
complexes in the ground and lowest excited states with higher spin multiplicity. Our calculations provide
rigorous theoretical confirmation that a positron can be attached to the excited states: 1s2s2p 4Po and
1s22s2p 3Po for eþ-Li and eþ-Be, respectively. The result is particularly notable for the eþ-Be complex,
as the excited 3Po state lies below the autoionization threshold. We report accurate binding energies,
annihilation rates and structural properties of these positron-atom systems. The existence of the ground
and metastable excited states with bound positron opens up a new route to the presently lacking
experimental verification of stability of a positron binding to any neutral atom