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Chemistry
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Recent Submissions
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(Beilstein Journal of Organic Chemistry, 2020-08)In this report, we introduce a new strategy for controlling the stereochemistry in Ugi adducts. Instead of controlling stereochemistry directly during the Ugi reaction we have attempted to stereodefine the chiral center ...
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(Public Library of Science, 2015-04)We present a general approach in 1H-detected 13C solid-state NMR (SSNMR) for side-chain signal assignments of 10-50 nmol quantities of proteins using a combination of a high magnetic field, ultra-fast magic-angle spinning ...
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(Nihon Bunseki Kagakkai, 2018)We demonstrated that a cost-efficient, easy to prepare, hybrid SERS substrate-gold nanoparticles (AuNPs) on untreated Al foil (AlF) can effectively detect pharmaceuticals, such as paracetamol and clinical biomarkers, like ...
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(Nazarbayev University School of Science and Technology, 2017-05-01)Raman and Brillouin spectroscopic provide with a powerful way to non-invasively assess both chemical and physical (viscoelastic) properties. In this report, Brillouin microspectroscopy was used for real time analysis of ...
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(MDPI, 2018-05-07)Convective instabilities in the advanced stages of nuclear shell burning can play an important role in neutrino-driven supernova explosions. In our previous work, we studied the interaction of vorticity and entropy waves ...
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(MDPI, 2018-05-18)In recent years, functional nanoprobes with multiple imaging modalities have become an emerging field of biomedical research. In this preliminary study, we utilized a facile hydrothermal method for the preparation of ...
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(Journal of Catalysis, 2016-12-01)Abstract The rare earth metal Ce-doped cobalt ferrite samples CexCo1−xFe2O4 (x=0.1, 0.3, 0.5) were prepared by the sol–gel autocombustion route. The as-prepared samples were characterized by X-ray diffractometry, scanning ...
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(Polyhedron, 2018-01-08)Abstract 4-Amino-2,1,3-benzothiadiazole (L) and its model complexes with Cu+, Zn2+, Ag+ and Cd2+ have been computationally investigated in order to reveal the origins of coordination preferences of this multidentate ligand. ...
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(Journal of Solid State Chemistry, 2016-01-01)Abstract The series of quaternary sulfides with general formula Ln2CuMS5 (Ln=La, Ce; M=Sb, Bi) have been synthesized by solid-state reactions. Three representative members have been structurally characterized by single-crystal ...
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(Electrochimica Acta, 2014-10-10)Abstract A novel porous sulfur/polypyrrole/multiwalled carbon nanotube composite (S/PPy/MWNT) was synthesized via in situ polymerization of pyrrole monomer with nano-sulfur and MWNT aqueous suspension followed by a low ...
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(Materials Today: Proceedings, 2017-01-01)Abstract We have synthesized amorphous silicon-nanomaterials displaying high capacity and stable cyclability using an original organometallic approach. The method is based on the decomposition of silicon compounds 1Si-P1-U-2016 ...
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(Journal of Organometallic Chemistry, 2016-08-15)Abstract Three compounds have been prepared in which a 4-aminochloroquinoline moiety is covalently linked to a cyclopentadienyl manganese tricarbonyl moiety. One of these (“cymanquine”, 4) is the analogue of the potent ...
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One-electron oxidation of chloroquine, cymanquine, and related aminoquinolines in nonaqueous media (Journal of Electroanalytical Chemistry, 2017-08-15)Abstract The anodic oxidation of a series of secondary-amine-substituted chloroquinoline derivatives, 1–5, has been studied in dichloromethane/0.05M [NBu4][B(C6F5)4]. Compounds 4 and 5 contain organometallic moieties of ...
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(Journal of Inorganic Biochemistry, 2017-01-01)Abstract In this work, hollow multiple-Ag-nanoclustes- C-shell nanocomposites (Ag@C) were synthesized by using silane coupling agent to graft carbon dots (CDs) with silver nanoparticles (AgNPs). CDs act as coating and ...
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(Tetrahedron, 2017-04-06)Abstract Chemoenzymatic synthesis and modification of well-defined macrolactonic sophorolipid (SLML) analogues via a series of successive regioselective de-esterification/transesterification reactions is investigated. Of ...
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(Journal of Organometallic Chemistry, 2017-05-15)The authors regret that the oxidation potentials given for compound 5 in the paper are incorrect. The correct values, referenced to ferrocene, are 0.88 V for the first oxidation and 1.14 V for the second oxidation.
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(Chemical Physics, 2015-09-08)Abstract We introduce a database of 20 accurate cycloreversion barrier heights of 5-membered heterocyclic rings (to be known as the CRBH20 database). In these reactions, dioxazole and oxathiazole rings are fragmented to ...
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(Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015-04-05)Abstract The use of theoretical techniques in the structural development of dye-sensitized solar cells helps in the efficient screening of the dyes. To properly rationalize the dye’s design process, benchmark calculations ...
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(Computational and Theoretical Chemistry, 2015-03-01)Abstract We report a computational modeling, based on DFT and TD-DFT methodologies, on the structural, electronic, and optical properties of different donor–acceptor co-polymer system in bulk heterojunction solar cells. ...
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(Chemical Data Collections, 2016-05-01)Abstract Knowledge of the energies required to induce homolytic cleavage of the C–Br bonds of brominated organic molecules, a process that affords carbon-centered radicals and Br•, is of fundamental importance. Although ...
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